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THE REACTIONS OF ARYLAZASYDNONES WITH S- AND O-NUCLEOPHILES

Александр В. Корманов, Татьяна К. Шкинева, Игорь Л. Далингер
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Abstract


A series of 3-arylazasydnone derivatives containing a chlorine atom and nitro group at various phenyl ring locations were functionalized by a method developed on the basis of reactions with different S- and O-nucleophiles. In all cases, an SNAr reaction was shown to occur where the leaving group could be either a halogen or azasydnone moiety, depending on their mutual position.

 


Keywords


азасиднон; нитроарилазасиднон; 1,2,3,4-оксатриазолий-5-олат; мезоионные соединения; нуклеофильное замещение; полиазотные гетероциклы.

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