

THE REACTIONS OF ARYLAZASYDNONES WITH S- AND O-NUCLEOPHILES

Abstract
A series of 3-arylazasydnone derivatives containing a chlorine atom and nitro group at various phenyl ring locations were functionalized by a method developed on the basis of reactions with different S- and O-nucleophiles. In all cases, an SNAr reaction was shown to occur where the leaving group could be either a halogen or azasydnone moiety, depending on their mutual position.
Keywords
азасиднон; нитроарилазасиднон; 1,2,3,4-оксатриазолий-5-олат; мезоионные соединения; нуклеофильное замещение; полиазотные гетероциклы.
Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv