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2-ISOXAZOLINES WITH AN ELECTRON-ACCEPTOR SUBSTITUENT AT C(5) IN REACTIONS WITH NUCLEOPHILIC REAGENTS

Е. В. Королева, Н. Ф. Бондарь, Я. М. Каток, Н. А. Чеканов, Т. В. Чернихова

Abstract


Depending on the substituent at position 5 of the  heterocycle, reaction of 2-isoxazolines with K-selectride, molybdenum hexacarbonyl, dimsyl sodium, and butyl lithium gave 1,3-cyclo-decomposition, aromatization of the isoxazoline ring, or reduction of the functional groups in the substituted isoxazolines.

 

How to Cite
Koroleva, E. V.; Bondar, N. F.; Katok, Ya. M.; Chekanov, N. A.; Chernikhova, T. V.  Chem. Heterocycl. Compd. 2007, 43, 362. [Khim. Geterotsikl. Soedin. 2007, 447.]

For this article in the English edition see DOI 10.1007/s10593-007-0053-6

 


Keywords


derivatives of 2-isoxazoline; dimsyl sodium; molybdenum hexacarbonyl; K-selectride; cyclodecomposition

Full Text: PDF (Russian) Supplementary File(s): None


 

 

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