PHENYLGLYOXAL DIHYDRAZONES AS UNEXPECTED PRODUCTS IN THE SYNTHESIS OF 1,2,4-TRIAZINES BY INTERACTION OF α-BROMOACETOPHENONES AND ARYLHYDRAZIDES

Authors

  • Д. С. Копчук Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
  • И. С. Ковалев Ural Federal University named after the First President of Russia B. N. Yeltsin
  • Г. В. Зырянов Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
  • А. Ф. Хасанов Ural Federal University named after the First President of Russia B. N. Yeltsin
  • А. С. Медведевских Ural Federal University named after the First President of Russia B. N. Yeltsin
  • В. Л. Русинов Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences
  • О. Н. Чупахин Ural Federal University named after the First President of Russia B. N. Yeltsin; I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/782

Keywords:

aromatic acid hydrazides, α-bromoacetophenone, phenylglyoxal dihydrazone, 1, 2, 4-triazine, condensation

Abstract

On interacting α-bromoacetophenones with aromatic carboxylic acid hydrazides, the formation of two reaction products was observed in certain cases, the expected 1,2,4-triazine and the phenylglyoxal dihydrazone as an unexpected product. The effect of substituents in the initial substrates and of the conditions of carrying out the synthesis on the direction of the reaction have been studied.

Authors: D. S. Kopchuk, I. S. Kovalev, G. V. Zyryanov, A. F. Khasanov, A. S. Medvedevskikh, V. L. Rusinov, and O. N. Chupakhin.

English Translation in Chemistry of Heterocyclic Compounds, 2013, 49 (7), pp 988-992

http://link.springer.com/article/10.1007/s10593-013-1336-8

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Published

2013-07-02

Issue

No. 7 (2013)

Section

Original Papers