SYNTHESIS AND STRUCTURE OF SCHIFF BASES DERIVED FROM 3-FORMYL-4-HYDROXYCOUMARIN AND DIAMINES

Authors

  • Б. Г. Милевский D. Mendeleev University of Chemical Technology of Russia
  • Т. А. Чибисова D. Mendeleev University of Chemical Technology of Russia
  • Н. П. Соловьева Center of Drug Chemistry
  • О. С. Анисимова Center of Drug Chemistry
  • В. С. Лебедев D. Mendeleev University of Chemical Technology of Russia
  • И. В. Иванов D. Mendeleev University of Chemical Technology of Russia
  • В. Ф. Травень D. Mendeleev University of Chemical Technology of Russia

DOI:

https://doi.org/10.1007/852

Keywords:

3-formyl-4-hydroxycoumarin, enamines, E/Z isomerization, tautomerism

Abstract

The mono- and diimine products from the condensation of 3-formyl-4-hydroxycoumarin and various diamines were synthesized. It was shown by 1H NMR and mass spectrometry that the obtained compounds in DMSO-d6 solution and in gas phase exist in the E- and Z-keto-enamine forms.

Authors: B. G. Milevskii, T. A. Chibisova, N. P. Solov'eva, O. S. Anisimova, V. S. Lebedev, I. V. Ivanov, and V. F. Traven

English Translation in Chemistry of Heterocyclic Compounds, 2013, 48 (12), pp 1781-1792

http://link.springer.com/article/10.1007/s10593-013-1209-1

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Published

2013-08-20

Issue

No. 12 (2012)

Section

Original Papers