STRUCTURE OF 5,6,7,8-TETRAFLUORO-4-HYDROXYCOUMARINS

Authors

  • К. В. Щербаков I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • Я. В. Бургарт I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • М. И. Кодесс I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • В. И. Салоутин I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/927

Keywords:

5, 6, 7, 8-tetrafluoro-4-hydroxycoumarin, imine-enamine tautomerism, keto-enol tautomerism

Abstract

The structure of 5,6,7,8-tetrafluoro-4-hydroxycoumarin and its 3-substituted derivatives was studied by X-ray structural analysis and IR, 1H, 13C, and 15N NMR spectroscopy. It was established that the nature of the substituent at the position 3 of the coumarin ring has a significant effect on its structure.

Authors: K. V. Shcherbakov, Ya. V. Burgart, M. I. Kodess, and V. I. Saloutin

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (9), pp 1297-1306

http://link.springer.com/article/10.1007/s10593-012-1136-6

Downloads

Published

2013-09-02

Issue

No. 9 (2012)

Section

Original Papers