CORRELATION OF THE HOMO-LUMO GAP IN FURYL AND THIENYL NITRONES AND NITROETHENES WITH THEIR ELECTROCHEMICAL REDOX POTENTIALS

Authors

  • M. Boulkroune Department of Chemistry, University Mentouri, 25000 Constantine, Algeria Pers. address: 122 Rue Kaddour Boumedous Bt D, Ciloc, Constantine, Algérie.
  • L. Ignatovich Laboratory of Metalloorganic Chemistry Latvian Institute of Organic Synthesis
  • V. Muravenko Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis
  • J. Spura Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis
  • A. Chibani Department of Chemistry, University Mentouri, 25000 Constantine, Algeria Pers. addresse: Cité Fadila Sâadane Bt F N° 11 Constantine 25000 Algérie
  • V. Jouikov UMR 6226 CPM, University of Rennes 1, 35042 Rennes, France Pers. address: 8 allée de Penmarch, 35700 Rennes, France

DOI:

https://doi.org/10.1007/966

Keywords:

organylsilylfuryl(thienyl)nitrones, organylsilylfuryl(thienyl)nitroethenes, IR spectroscopy, 1H, 13C, 29Si NMR spectroscopy, electrochemical redox potentials, synthesis

Abstract

Two series of potentially biologically active heteroaryl derivatives of nitrones and nitroethenes have been prepared and studied by cyclic voltammetry and DFT modeling. Satisfactory correlations of experimental first peak potentials Ep, both in oxidation and in
reduction, with the energies of the corresponding frontier orbitals were found.

How to Cite
Boulkroune, M.; Ignatovich, L.; Muravenko, V.; Spura, J.; Chibani, A.; Jouikov, V. Chem. Heterocycl. Compd. 2014, 49, 1579. [Khim. Geterotsikl. Soedin. 2013, 1706.]

For this article in the English edition see DOI 10.1007/s10593-014-1409-3

Author Biographies

M. Boulkroune, Department of Chemistry, University Mentouri, 25000 Constantine, Algeria Pers. address: 122 Rue Kaddour Boumedous Bt D, Ciloc, Constantine, Algérie.

Mina Boulkroune

L. Ignatovich, Laboratory of Metalloorganic Chemistry Latvian Institute of Organic Synthesis

Luba Ignatovich

V. Muravenko, Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis

Velta Muravenko

J. Spura, Laboratory of Organometallic Chemistry Latvian Institute of Organic Synthesis

Jana Spura

A. Chibani, Department of Chemistry, University Mentouri, 25000 Constantine, Algeria Pers. addresse: Cité Fadila Sâadane Bt F N° 11 Constantine 25000 Algérie

Aissa

V. Jouikov, UMR 6226 CPM, University of Rennes 1, 35042 Rennes, France Pers. address: 8 allée de Penmarch, 35700 Rennes, France

Viatcheslav Jouikov

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Published

2013-10-22

Issue

No. 11 (2013)

Section

Original Papers