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CORRELATION OF THE HOMO-LUMO GAP IN FURYL AND THIENYL NITRONES AND NITROETHENES WITH THEIR ELECTROCHEMICAL REDOX POTENTIALS

M. Boulkroune, L. Ignatovich, V. Muravenko, J. Spura, A. Chibani, V. Jouikov
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Abstract


Two series of potentially biologically active heteroaryl derivatives of nitrones and nitroethenes have been prepared and studied by cyclic voltammetry and DFT modeling. Satisfactory correlations of experimental first peak potentials Ep, both in oxidation and in
reduction, with the energies of the corresponding frontier orbitals were found.

How to Cite
Boulkroune, M.; Ignatovich, L.; Muravenko, V.; Spura, J.; Chibani, A.; Jouikov, V. Chem. Heterocycl. Compd. 2014, 49, 1579. [Khim. Geterotsikl. Soedin. 2013, 1706.]

For this article in the English edition see DOI 10.1007/s10593-014-1409-3


Keywords


organylsilylfuryl(thienyl)nitrones; organylsilylfuryl(thienyl)nitroethenes; IR spectroscopy; 1H, 13C, 29Si NMR spectroscopy; electrochemical redox potentials; synthesis

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