Study of the extraction of strontium(II) and lead(II) by crown and dithiacrown ethers

Authors

  • А. А. Абрамов M. V. Lomonosov Moscow State University, 119899 Moscow
  • H. B. Аверина M. V. Lomonosov Moscow State University, 119899 Moscow
  • Б. З. Иофа M. V. Lomonosov Moscow State University, 119899 Moscow
  • B. B. Самошин M. V. Lomonosov Moscow State University, 119899 Moscow
  • H. А. Иванова M. V. Lomonosov Moscow State University, 119899 Moscow
  • Ю. А. Сапожников M. V. Lomonosov Moscow State University, 119899 Moscow
  • H. C. Зефиров M. V. Lomonosov Moscow State University, 119899 Moscow

Abstract

A study was carried out on the extraction of strontium(II) and lead(II) picrates by chloroform solutions of crown and dithiacrown ethers. The benzene ring substituents in benzodithia-18-crown-6 only slightly affect the extraction of strontium and lead cations and their separation. The introduction of an adamantyl group onto the benzene ring markedly increases the extraction of lead and the separation selectivity of these cations. The use of dithia derivatives of benzo-18-crown-6 is less efficient for the extraction of both strontium and lead, though the selectivity of their separation is almost the same as in the extraction with benzo-18-crown-6.

How to Cite
Abramov, A. A.; Averina, N. V.; Iofa, B. Z.; Samoshin, V. V; Ivanova, N. A.; Sapozhnikov, Yu. A.; Zefirov, N. S. Chem. Heterocycl. Compd. 1997, 33, 982. [Khim. Geterotsikl. Soedin. 1997, 1125.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02253174

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Published

1997-08-25

Issue

No. 8 (1997)

Section

Original Papers