Chemistry of furazano[3,4-<i>b</i>]pyrazines. 2. Nucleophilic substitution of the azido group in furazano[3,4-<i>b</i>]pyrazines

Authors

  • B. Г. Андрианов Latvian Institute of Organic Synthesis
  • И. Б. Старченков Latvian Institute of Organic Synthesis
  • А. Ф. Мишнев Latvian Institute of Organic Synthesis

Abstract

The corresponding 7-substituted furazano[3,4-b]tetrazolo[1,2-d]pyrazines were obtained by nucleophilic substitution of the azido group in 7-azidofurazano[3,4-b]tetrazolo[1,2-d]pyrazine. It was shown that these compounds exist in the tetrazole form in the crystalline state; in solutions, a tautomeric equilibrium is observed between the azide and tetrazole forms. Further reaction with nucleophiles leads to the production of 5,6-disubstituted furazano[3,4-b]pyrazines.

How to Cite
Andrianov, V. G.; Starchenkov, I. B.; Mishnev, A. F. Chem. Heterocycl. Compd. 1997, 33, 977. [Khim. Geterotsikl. Soedin. 1997, 1120.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02253173

Published

1997-08-25

Issue

Section

Original Papers