Oxidation reactions of azines. 4. Conjugation of 4-aryl-1,2,5,6-tetrahydropyridines with compounds containing an activated methyl group. Synthesis and structure of 2-acylmethylene- and 2-nitromethylene-1,2,5,6-tetrahydropyridines

Authors

  • A. T. Солдатенкoв Russian University of National Friendship, Moscow 117198
  • И. А. Бекpо Russian University of National Friendship, Moscow 117198
  • Ж. А. Мамырбекова Russian University of National Friendship, Moscow 117198
  • C. А. Солдатовa Russian University of National Friendship, Moscow 117198
  • Э. Гловер Russian University of National Friendship, Moscow 117198
  • H. Д. Сергеева Russian University of National Friendship, Moscow 117198
  • Л. H. Кулешова Russian University of National Friendship, Moscow 117198
  • B. H. Хрусталев Russian University of National Friendship, Moscow 117198

Abstract

A novel Csp3−Csp3 oxidative conjugation with compounds containing an activated methylene group has been described in the case of 1-alkyl-4-aryl-1,2,5,6-tetrahydropyridines. It was shown that treatment of the indicated Δ3-piperidienes with methyl ketones or nitromethane in the presence of KMnO4 gives their 2-acylmethylene-or 2-nitromethylene derivatives respectively.

How to Cite
Soldatenkov, A. T.; Bekro, I. A.; Mamyrbekova, Z. A.; Soldatova, S. A.; Glover, E.; Sergeeva, N. D.; Kuleshova, L. N.; Khrustalev, V. N. Chem. Heterocycl. Compd. 1997, 33, 571. [Khim. Geterotsikl. Soedin. 1997, 659.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF02291941

Downloads

Published

1997-05-25

Issue

No. 5 (1997)

Section

Original Papers