Reaction of 2-cyanoethane-1,1,2-tricarboxamide with α-alkylacroleins

Authors

  • О. E. Hасaкин I. N. Ul'yanov Chuvash State University, Cheboksary 428015
  • В. В. Павлов I. N. Ul'yanov Chuvash State University, Cheboksary 428015
  • А. Н. Лыщиков I. N. Ul'yanov Chuvash State University, Cheboksary 428015
  • П. M. Лукин I. N. Ul'yanov Chuvash State University, Cheboksary 428015
  • В. Н. Хрустaлев I. N. Ul'yanov Chuvash State University, Cheboksary 428015
  • M. Ю. Антипин I. N. Ul'yanov Chuvash State University, Cheboksary 428015
  • Я. Г. Уpман A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow 117813

Abstract

In the presence of catalytic amounts of triethylamine 2-cyanoethane-1,1,2-tricarboxamide forms Michael adducts with α-alkylacroleins. After two intramolecular cyclizations, the adducts are converted into 5-alkyl-6-amino-4-hydroxy-7-carbamoyl-2-oxo-1-cyano-3-azabicyclo[3.2.1]oct-6-enes.

How to Cite
Nasakin, O. E.; Pavlov, V. V.; Lyshchikov, A. N.; Lukin, P. M.; Khrustalev, V. N.; Antipin, N. Yu.; Urman, A. G. Chem. Heterocycl. Compd. 1996, 32, 1136. [Khim. Geterotsikl. Soedin. 1996, 1326.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01169222

Published

1996-10-25

Issue

Section

Original Papers