SYNTHESIS AND CONVERSIONS OF 2-ACETYL-5-METHYL-4-NITROFURAN. ISOMERIZATION AND BECKMAN REARRANGEMENT OF THE OXIME

Authors

  • H. O. Салдабол Latvian Institute of Organic Synthesis
  • В. А. Славинская Latvian Institute of Organic Synthesis
  • Э. Э. Лиепиньш Latvian Institute of Organic Synthesis
  • Ю. Ю. Попелис Latvian Institute of Organic Synthesis
  • И. Б. Мажейка Latvian Institute of Organic Synthesis

DOI:

https://doi.org/10.1007/1099

Abstract

2-Acetyl-5-methyl-4-nitrofuran and 3,5-dinitro-α-methylfuran were obtained by the reaction of 70% nitric acid with 2-acetyl-5-methylfuran, its oxime and semicarbazone in concentrated H2SO4. ω-Bromonitro ketone and a series of 5-methyl-4-nitro-2-furyl-substituted azaheterocyclic compounds based on it were obtained.

Authors: N. O. Saldabol, V. A. Slavinskaya, E. E. Liepinsh, Yu. Yu. Popelis, and I. B. Mazheika.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (12), pp 1415-1422

http://link.springer.com/article/10.1007/BF02251814

Downloads

Published

2013-11-01

Issue

No. 12 (1999)

Section

Original Papers