Synthesis of rigidly linked triad molecules based on octaalkylporphyrin, capable of multistep electron transfer

Authors

  • А. А. Грибков M. V. Lomonosov State Academy of Fine Chemical Technology, Moscow 117571
  • В. В. Боровков M. V. Lomonosov State Academy of Fine Chemical Technology, Moscow 117571
  • Р. П. Евстигнеева M. V. Lomonosov State Academy of Fine Chemical Technology, Moscow 117571
  • Е. Саката Institute of Scientific and Industrial Research, 567, Osaka

Abstract

We have designed and carried out the synthesis of triad model systems containing octaalkylporphyrin, benzoquinone, and trichlorobenzoquinone with an oxidation-reduction potential gradient in the molecule. The quinone moieties are fixed relative to the porphyrin using spiro[4,4]nonane and methylene spacers.

How to Cite
Gribkov, A. A.; Borovkov, V. V.; Evstigneeva, R. P.; Sakata, E. Chem. Heterocycl. Compd. 1994, 30, 905. [Khim. Geterotsikl. Soedin. 1994, 1052.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01165028

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Published

1994-08-25

Issue

No. 8 (1994)

Section

Original Papers