Reactions of polyhalopyridines. 7. New method of synthesizing carbonyl-containing derivatives of polychloropyridine-2-thiols

Authors

  • А. М. Сипягин Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • В. B. Колчанов Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432
  • H. H. Свешников Institute of Chemical Physics at Chernogolovka, Russian Academy of Sciences, Chernogolovka 142432

Abstract

A method of synthesizing S-alkylcarbonyl and dicarbonyl substituted polychloropyridine-2-thiols has been developed which is based on the thermally induced decomposition of N,N-dimethyldithiocarbamate derivatives of polychloropyridine N-oxides in the presence of carbonyl compounds. Various pathways were shown for the thermolysis of the starting materials depending on the number of chlorine atoms in the pyridine nucleus.

How to Cite
Sipyagin, A. M.; Kolchanov, V. V.; Sveshnikov, N. N. Chem. Heterocycl. Compd. 1994, 30, 579. [Khim. Geterotsikl. Soedin. 1994, 660.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01169839

Published

1994-05-25

Issue

Section

Original Papers