Molecular and crystal structure of 1-bromo-1-butyl-3H-2,1-benzoxatellurole

Authors

  • А. А. Максименко Scientific Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don 344090
  • И. Д. Садеков Scientific Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don 344090
  • O. E. Компан Scientific Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don 344090
  • В. И. Минкин Scientific Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don 344090
  • Ю. T. Стручков Scientific Research Institute of Physical and Organic Chemistry, Rostov State University, Rostov-on-Don 344090

Abstract

The molecular and crystal structure of 1-bromo-1-butyl-3H-2,1-benzoxatellurole was determined by X-ray diffraction structural analysis. Without taking account of secondary interactions, the molecule contains a tetracoordinated tellurium atom with bisphenoidal bond configuration. The angle between the axial bromine and oxygen atoms is 172.1°. The intermolecular Te...Br contacts (3.592 Å) connect the individual dimers into planar dieters, which expands the coordination about the tellurium atom to octahedral.

How to Cite
Maksimenko, A. A.; Sadekov, I. D.; Kompan, O. E.; Minkin, V. I.; Struchkov, Yu. T. Chem. Heterocycl. Compd. 1994, 30, 367. [Khim. Geterotsikl. Soedin. 1994, 417.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01165709

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Published

1994-03-25

Issue

No. 3 (1994)

Section

Original Papers