Synthesis and properties of <i>sym</i>-triazene derivatives 12. Synthesis of 2,4-bis(trichloromethyl)-6-substituted <i>sym</i>-triazenes containing a sterically hindered phenol group

Authors

  • B. И. Келарев I. M. Gubkin State Oil and Gas Academy, Moscow 117917
  • B. Н. Кошелев I. M. Gubkin State Oil and Gas Academy, Moscow 117917
  • Н. B. Белов I. M. Gubkin State Oil and Gas Academy, Moscow 117917
  • O. B. Малова I. M. Gubkin State Oil and Gas Academy, Moscow 117917
  • P. А. Караханов I. M. Gubkin State Oil and Gas Academy, Moscow 117917

Abstract

6-Substituted 2,4-bis(trichloromethyl)-sym-triazines containing the 2,6-di-tert-butylphenol group are synthesized by simultaneous cyclotrimerization of trichloroacetonitrile with the nitrile or thiocyanate derivative of the sterically hindered phenol in the presence of gaseous HCl. Significant amounts of 2,4,6-tris(trichloromethyl)-sym-triazine are formed as a byproduct.

How to Cite
Kelarev, V. I.; Koshelev, V. N.; Belov, N. V.; Malova, O. V.; Karakhanov, R. A. Chem. Heterocycl. Compd. 1994, 30, 218. [Khim. Geterotsikl. Soedin. 1994, 240.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01165016

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Published

1994-02-25

Issue

No. 2 (1994)

Section

Original Papers