X-ray emission spectroscopy and electronic structure of heterocyclic compounds. 3. Pyrrole

Authors

  • B. Д. Юматов Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk
  • H. П. Ерчак Latvian Institute of Organic Synthesis, Riga LV-1006
  • Э. Лукевиц Latvian Institute of Organic Synthesis, Riga LV-1006

Abstract

The electronic structure of the pyrrole molecule has been investigated by X-ray emission spectroscopy. The NKα and CKα spectra have been recorded. The theoretical spectra were prepared on the basis of non-empirical calculations. The structure of the HOMO was investigated similarly. The particularly high resolution in the CKα spectrum permitted the identification of the X-ray transitions from the upper orbitals to the atomic orbitals of carbon atoms in different positions relative to the nitrogen atom.

How to Cite
Yumatov, V. D.; Erchak, N. P.; Lukevits, É. Chem. Heterocycl. Compd. 1993, 29, 1142. [Khim. Geterotsikl. Soedin. 1993, 1333.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF00538057

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Published

1993-10-25

Issue

No. 10 (1993)

Section

Original Papers