BENZAZOLES. 5. SYNTHESIS AND ARYLSULFONYLATION OF 1-HYDROXYMETHYLBENZIMIDAZOLE

Authors

  • К. Б. Абдиреймов S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan
  • Н. С. Мухамедов S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan
  • М. Ж. Айымбетов S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan
  • Х. М. Шахидоятов S. Yu. Yunusov Institute of the Chemistry of Plant Substances, Academy of Sciences of Uzbekistan

DOI:

https://doi.org/10.1007/1238

Keywords:

1-arylsulfonylbenzimidazoles, 1-hydroxymethylbenzimidazole, arylsulfonylation, hydroxymethylation, deformylation

Abstract

1-Hydroxymethylbenzimidazole was synthesized by the reaction of benzimidazole with formaldehyde. Arylsulfonylation of the former in the presence of triethylamine occurred anomalously with deformylation to give 1-arylsulfonylbenzimidazoles in place of the expected 1-arylsulfonyloxymethyl-benzimidazoles.

Authors: K. B. Abdireimov, N. S. Mukhamedov, M. Zh. Aiymbetov, and Kh. M. Shakhidoyatov.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (3), pp 458-461

http://link.springer.com/article/10.1007/s10593-012-1015-1

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Published

2013-11-26

Issue

No. 3 (2012)

Section

Original Papers