2-AMINO-5-ARYL- AND 2-AMINO-5-HETARYL-3-CYANO-6-(2-THIENYL)PYRIDINES AS ORGANIC DYES FOR DYE-SENSITIZED SOLAR CELLS: SYNTHESIS, QUANTUM-CHEMICAL CALCULATIONS, SPECTRAL AND ELECTROCHEMICAL PROPERTIES

Authors

  • Е. В. Вербицкий I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin
  • П. А. Слепухин I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • Ю. О. Субботина I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin
  • М. С. Валова I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • А. В. Щепочкин I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • Е. М. Чепракова I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences
  • Г. Л. Русинов I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin
  • В. Н. Чарушин I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin

DOI:

https://doi.org/10.1007/1744

Keywords:

dyes, pyridines, pyrimidines, dye-sensitized solar cells

Abstract

Novel organic dyes containing pyridine ring as the anchoring group with carbazole or triphenylamine substituents were synthesized from available 4-(2-thienyl)pyrimidine using the Kost–Sagitullin rearrangement and Suzuki cross coupling assisted by microwave irradiation. The photophysical (absorption and photoluminescence spectra) and electrochemical properties of these compounds were investigated. The data from quantum calculations show that all of the dyes are potentially good photosensitizers for dye-sensitized solar cells.

How to Cite
Verbitskiy, E. V.; Slepukhin, P. A.; Subbotina, Yu. O.; Valova, M. S.; Schepochkin, A. V.; Cheprakova, E. M.; Rusinov, G. L.; Charushin, V. N. Chem. Heterocycl. Compd. 2014, 50, 814. [Khim. Geterotsikl. Soedin. 2014, 883.]

For this article in the English edition see DOI 10.1007/s10593-014-1536-x

Author Biography

Е. В. Вербицкий, I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences; Ural Federal University named after the First President of Russia B. N. Yeltsin

Егор Владимирович Вербицкий

Старший научный сотрудник лаборатории гетероциклических соединений

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Published

2014-06-30

Issue

No. 6 (2014)

Section

Original Papers