SYNTHESIS OF [1,2,3]TRIAZOLO[1,5-<i>a</i>]PYRAZINIUM-3-OLATES

Authors

  • Ю. И. Нейн Ural Federal University named after the First President of Russia B. N. Yeltsin
  • Ю. Ю. Моржерин Ural Federal University named after the First President of Russia B. N. Yeltsin

DOI:

https://doi.org/10.1007/1767

Keywords:

condensed ring systems, mesoionic heterocycles, 1, 2, 3-triazoles, cyclization

Abstract

4-Carbamoyl-3-cyanomethyl-1,2,3-triazolium-5-olates were shown to cyclize when treated with sodium ethoxide giving zwitterionic 6-amino-4-oxo-4,5-dihydro-2Н‑1,2,3-triazolo[1,5-а]pyrazinium-3-olates. In contrast to 4-carbamoyl-3‑cyanomethyl-1,2,3-triazolium-5-olates, 4-carbamoyl-3‑phenacyl-1,2,3-triazolium-5‑olates cyclized only by the action of phosphoric acid.

How to Cite
Nein, Yu. I.; Morzherin, Yu. Yu. Chem. Heterocycl. Compd. 2014, 50, 1021. [Khim. Geterotsikl. Soedin. 2014, 1107.]

For this article in the English edition see DOI 10.1007/s10593-014-1558-4

Author Biographies

Ю. И. Нейн, Ural Federal University named after the First President of Russia B. N. Yeltsin

Юлия Ивановна Нейн

доцент кафедры технологии органического синтеза химико-технологический институт Уральского федерального университета

Ю. Ю. Моржерин, Ural Federal University named after the First President of Russia B. N. Yeltsin

Юрий Юрьевич Моржерин

профессор кафедры технологии органического синтеза УрФУ

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Published

2014-08-04

Issue

No. 7 (2014)

Section

Original Papers