MICROWAVE-ASSISTED SYNTHESIS OF NOVEL PERIMIDINIUM SALTS AS <i>N</i>-HETEROCYCLIC CARBENE PRECURSORS: INVOLVEMENT IN PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS

Authors

  • Gulnihan Onar Department of Chemistry, Faculty of Arts and Sciences, Inonu University
  • Mert Olgun Karataş Department of Chemistry, Faculty of Arts and Sciences, Inonu University
  • Bülent Alici Department of Chemistry, Faculty of Arts and Sciences, Inonu University
  • Engin Cetinkaya Department of Chemistry, Faculty of Sciences, Ege University

DOI:

https://doi.org/10.1007/2252

Keywords:

carbenes, palladium, perimidine, catalysis, Heck reaction, microwave irradiation, Suzuki reaction

Abstract

In the current study five novel perimidinium chlorides were synthesized in good yields by reaction of 1-(3-methylbenzyl)perimidine with five different alkyl chlorides under microwave irradiation in 30 minutes. Synthesized compounds were characterized by IR, 1H, 13C NMR spectroscopic methods and elemental analyses. Performance of in situ formed catalytic system which consist of the perimidinium salts and Pd(OAc)2 was investigated for Heck and Suzuki reactions in aqueous media and desired products were obtained in good yields.

How to Cite
Onar, G.; Karatas, M. O.; Alici, B.; Cetinkaya, E. Chem. Heterocycl. Compd. 2015, 51, 563. [Khim. Geterotsikl. Soedin. 2015, 51, 563.]

For this article in the English edition see DOI 10.1007/s10593-015-1732-3

Author Biography

Mert Olgun Karataş, Department of Chemistry, Faculty of Arts and Sciences, Inonu University

Department Of Chemistry

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Published

2015-05-20

Issue

Vol. 51 No. 6 (2015)

Section

Original Papers