Synthesis of γ-sultones based on conversion of adamantane-type olefins
DOI:
https://doi.org/10.1007/2447Keywords:
adamantane, allyl bromides, homoadamantane, sultones, cage compounds, unsaturated compoundsAbstract
γ-Sultones condensed with the homoadamantane polycycle were synthesized by sulfonation of 1-(adamant-1-yl)-substituted olefins. The formation of γ-sultones containing a substituent at the α-position to the sulfonyl group occurs stereospecifically: 1Н and 13С NMR data support the formation of only the threo diastereomer.
How to Cite
Baimuratov, M. R.; Leonova, M. V.; Rybakov, V. B.; Klimochkin, Yu. N. Chem. Heterocycl. Compd. 2015, 51, 582. [Khim. Geterotsikl. Soedin. 2015, 51, 582.]
For this article in the English edition see DOI 10.1007/s10593-015-1740-3