SYNTHESIS OF <i>N</i>-HETEROARYLAMIDINES OF 1,2,3-THIADIAZOLE-4-CARBOXYLIC ACID FROM 2-CYANOTHIOACETAMIDES AND 5-AZIDO-1-METHYL-4-NITROIMIDAZOLE

Authors

  • Николай А. Беляев Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg 620002
  • Татьяна В. Березкина Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg 620002
  • Василий А. Бакулев Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg 620002

DOI:

https://doi.org/10.1007/2826

Keywords:

azides, cyanothioacetamides, imidazoles, 1, 2, 3-thiadiazoles, thioamides, 3-triazoles, Cornforth rearrangement

Abstract

The reaction of 2-cyanothioacetamides with 5-azido-1-methyl-4-nitroimidazole in ethanol in the presence of sodium ethoxide at 0°С lead to the formation of previously unknown N-heteroarylamidines of 1,2,3-thiadiazole-4-carboxylic acid in 58–76% yields.

How to Cite
Belyaev, N. A.; Beryozkina, T. V.; Bakulev, V. A. Chem. Heterocycl. Compd. 2016, 52, 206. [Khim. Geterotsikl. Soedin. 2016, 52, 206.]

For this article in the English edition see DOI 10.1007/s10593-016-1861-3

Author Biographies

Николай А. Беляев, Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg 620002

The chief of the technologyfor Organic Synthesis Department

Татьяна В. Березкина, Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg 620002

Татьяна Владимировна Березкина

старший научный сотрудник кафедры технологии органического синтеза

Василий А. Бакулев, Ural Federal University named after the first President of Russia B. N. Yeltsin, 19 Mira St., Yekaterinburg 620002

Василий Алексеевич Бакулев

заведующий кафедрой технологии органического синтеза

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Published

2016-04-11

Issue

Vol. 52 No. 3 (2016)

Section

Letters to the Editor