REACTIONS OF 1-TRICHLOROMETHYL-2,4,6-TRIMETHYLBENZENE WITH 2-AMINO- AND 2-AMINO-5-BROMOPYRIDINES

Authors

  • И. С. Поддубный N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • Л. И. Беленький N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
  • М. М. Краюшкин N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/386

Keywords:

2-aminopyridine, 2-amino-5-bromopyridine, 1-[α-(5-bromo-2-pyridylimino)-2, 4, 6-trimethyl]-5-bromo-2-pyridonimine, 1-trichloromethyl-2, 6-trimethylbenzene (mesitotrichloride), 1-[α-(2-pyridylimino)-2, 6-trimethylbenzyl]-2-pyridonimine, reactions with 1-trichloromethyl-2, 6-trimethylbenzene

Abstract

A new type of reaction has been discovered for trichloromethylarenes with pyridines. The reaction of 1 trichloromethyl-2,4,6-trimethylbenzene with 2-amino- and 2-amino-5-bromopyridines does not stop with formation of the pyridinium salt, but rather leads to unique amidines, namely, 1-[α-(2-pyridylimino)-2,4,6-trimethylbenzyl]-2-pyridonimine and its 5-bromo derivative.

Authors: I. S. Poddubnyi, L. I. Belen'kii, and M. M. Krayushkin.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (10), pp 1169-1171

http://link.springer.com/article/10.1023/A%3A1002864531871

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Published

2013-03-12

Issue

No. 10 (2000)

Section

Original Papers