Fe(CrO<sub>2</sub>)<sub>2</sub>–CATALYZED, PHOTOACTIVATED OXIDATIVE ONE-POT TANDEM SYNTHESIS OF SUBSTITUTED QUINOLINES FROM PRIMARY ALCOHOLS AND ARYLAMINES

Authors

  • Aynur R. Makhmutov Bashkir State University, 32 Z. Validi St., Ufa 450076
  • Akhat G. Mustafin Bashkir State University, 32 Z. Validi St., Ufa 450076
  • Salavat M. Usmanov Bashkir State University, 32 Z. Validi St., Ufa 450076

DOI:

https://doi.org/10.1007/4303

Keywords:

arylamines, primary alcohols, substituted quinolines, iron-containing catalyst, photoactivation

Abstract

A one-pot tandem synthesis of substituted quinolines involving selective catalytic oxidation of primary alcohols to the corresponding aldehydes and their subsequent condensation with arylamines has been developed. Fe(CrO2)2 has been used as a catalyst, and oxidation has been performed with aqueous H2O2. To accelerate the catalytic oxidation of alcohols, photoactivation method has been applied.

Author Biographies

Aynur R. Makhmutov, Bashkir State University, 32 Z. Validi St., Ufa 450076

Associate Professor of the Department of Chemistry(к.х.н., доцент кафедры химии)

Akhat G. Mustafin, Bashkir State University, 32 Z. Validi St., Ufa 450076

Professor of the Department of Physical Chemistry(д.х.н., профессор кафедры физической химии)

Salavat M. Usmanov, Bashkir State University, 32 Z. Validi St., Ufa 450076

Professor,
director of the Birsk branch of Bashkir State University(д.ф.-м..н., профессор, директор Бирского филиала БашГУ)

Downloads

Published

2018-05-16

Issue

Vol. 54 No. 3 (2018): Metal-catalyzed synthesis of heterocycles

Section

Original Papers