SYNTHESIS OF CHIRAL SPIRODIAZAFLUORENES

Authors

  • Юлия П. Устименко N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Academician Lavrentiev Ave., Novosibirsk 630090, Russia
  • Евгений C. Васильев N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Academician Lavrentiev Ave., Novosibirsk 630090, Russia
  • Сергей Н. Бизяев N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Academician Lavrentiev Ave., Novosibirsk 630090, Russia
  • Татьяна В. Рыбалова N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Academician Lavrentiev Ave., Novosibirsk 630090, Russia
  • Алексей В. Ткачёв N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Academician Lavrentiev Ave., Novosibirsk 630090, Russia Department of Natural Sciences, Novosibirsk State University, Novosibirsk 630090, Russia

DOI:

https://doi.org/10.1007/5857

Keywords:

chiral bipyridyls, chiral pyridines, diazafluorenes, spiro compounds, terpenes, chirality, donor-acceptor systems, electrophilic alkylation.

Abstract

Reactions of chiral nopinane-annulated diazafluorenone with substituted phenols and naphthols by the action of trifluoromethanesulfonic acid led to spiro products. The structure of the resorcinol derivative was confirmed by X-ray structural analysis.

Author Biography

Евгений C. Васильев, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, 9 Academician Lavrentiev Ave., Novosibirsk 630090, Russia

доп. адрес Vasilyev@nioch.nsc.ru

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Published

2020-11-26

Issue

Vol. 56 No. 11 (2020)

Section

Original Papers