SYNTHESIS OF NOVEL 2-HETARYLPYRROLIDINES <i>VIA</i> THE REACTION OF <i>N</i>-(4,4-DIETHOXYBUTYL)AMIDOPHOSPHATES WITH C-NUCLEOPHILES

Authors

  • Андрей В. Смолобочкин A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center” of the Russian Academy of Sciences, 8 Akademika Arbuzova St., Kazan 420088, Russia
  • Рахымжан А. Турманов Kazan National Research Technological University, 68 Karla Marksa St., Kazan 420015, Russia
  • Альмир С. Газизов A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center” of the Russian Academy of Sciences, 8 Akademika Arbuzova St., Kazan 420088, Russia
  • Елизавета А. Кузнецова Alexander Butlerov Institute of Chemistry, Kazan Federal University, 29/1 Kremlyovskaya St., Kazan 420008, Russia
  • Александр Р. Бурилов A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center” of the Russian Academy of Sciences, 8 Akademika Arbuzova St., Kazan 420088, Russia
  • Михаил А. Пудовик A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center” of the Russian Academy of Sciences, 8 Akademika Arbuzova St., Kazan 420088, Russia

DOI:

https://doi.org/10.1007/5892

Keywords:

N-(4, 4-diethoxybutyl)amidophosphate, 2-hetarylpyrrolidines, trifluoroacetic acid, heterocyclization.

Abstract

The reactions of N-(4,4-diethoxybutyl)amidophosphates with С-nucleophiles in chloroform in the presence of trifluoroacetic acid provided new 2-hetarylpyrrolidines. The reaction proceeded under mild conditions and gave good yields in the absence of metal-based catalysts.

Author Biography

Андрей В. Смолобочкин, A. E. Arbuzov Institute of Organic and Physical Chemistry, Federal Research Center “Kazan Scientific Center” of the Russian Academy of Sciences, 8 Akademika Arbuzova St., Kazan 420088, Russia

Научный сотрудник лаборатории элементорганического синтеза им. А.Н. Пудовика Института органической и физической химии им. А.Е. Арбузова ФИЦ Казанский научный центр РАН.

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Published

2020-11-05

Issue

Vol. 56 No. 10 (2020)

Section

Short Communications