SYNTHESIS AND TRANSFORMATIONS OF <i>N</i>-BUTYL-3(5)-NITRO-1,2,4-TRIAZOLES UNDER THE CONDITIONS OF ACID-CATALYZED ALKYLATION OF 3(5)-NITRO-1<i>H</i>-1,2,4-TRIAZOLES WITH BUTYL ALCOHOLS

Authors

  • Геннадий Т. Суханов Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia
  • Ирина А. Крупнова Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia
  • Юлия В. Филиппова Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia
  • Юрий В. Гатилов N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090, Russia
  • Анна Г. Суханова Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia
  • Константин К. Босов Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia
  • Екатерина В. Пивоварова Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

DOI:

https://doi.org/10.1007/5980

Keywords:

1-(tert-butyl)-4-(sec-butyl)-3-nitro-1, 2, 4-triazolium salt, 1-(sec-butyl)-3, 5-dinitro-1H-1, 4-triazole, N-(sec-butyl)-3(5)-nitro-1, alkylation, isomers, transformation of alkyl substituent, X-ray structural analysis.

Abstract

The directions of thermodynamically controlled rearrangements and transformations of alkyl substituents under the conditions of acidcatalyzed
alkylation of unsubstituted and 5(3)-substituted 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols (n-, i-, tert-, sec-BuOH) were studied.

Author Biographies

Геннадий Т. Суханов, Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

Лаборатория Химии и технологии высокоэнергетических азолов, главный научный сотрудник, д.х.н.

Ирина А. Крупнова, Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

Лаборатория Химии и технологии высокоэнергетических азолов, младший научный сотрудник

Юлия В. Филиппова, Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

Лаборатория Химии и технологии высокоэнергетических азолов, старший научный сотрудник, к.х.н.

Юрий В. Гатилов, N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 Akademika Lavrentieva Ave., Novosibirsk 630090, Russia

Руководитель группы рентгеноструктурного анализа НИОХ СО РАН, ведущий научный сотрудник, д.х.н.

Анна Г. Суханова, Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

Лаборатория Химии и технологии высокоэнергетических азолов, заведующий лабораторией, к.х.н.

Константин К. Босов, Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

Лаборатория Химии и технологии высокоэнергетических азолов, старший научный сотрудник, к.х.н.

Екатерина В. Пивоварова, Institute for Problems of Chemical and Energy Technologies, Siberian Branch of the Russian Academy of Sciences, 1 Sotsialisticheskaya St., Biysk 659322, Russia

Лаборатория Химии и технологии высокоэнергетических азолов, младший научный сотрудник, аспирант

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Published

2020-11-26

Issue

Vol. 56 No. 11 (2020)

Section

Original Papers