A NEW STRAIGHTFORWARD APPROACH TO 3-(ARYLIDENEAMINO)HYDANTOINS

Authors

  • Alexander N. Yankov N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia
  • Anatoly D. Shutalev N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

DOI:

https://doi.org/10.1007/5999

Keywords:

3-(arylideneamino)hydantoins, α-(4-semicarbazono)nitriles, 4-(tosylmethyl)semicarbazones, α-amidoalkylation.

Abstract

A novel straightforward approach to 3-(arylideneamino)hydantoins has been developed. It is based on the reaction of readily available 4-(tosylmethyl)semicarbazones with NaCN in DMF followed by heating of the obtained 4-(cyanomethyl)semicarbazones with concd HCl.

Author Biography

Alexander N. Yankov, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991, Russia

Кафедра органической химии, заведующий

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Published

2020-12-18

Issue

Vol. 56 No. 12 (2020)

Section

Original Papers