SYNTHESIS AND REACTIONS OF METHYL 3-(1-ADAMANTYLCARBONYL)-4,5-DIHYDRO-1H-PYRAZOLE-5-CARBOXYLATE

Authors

  • С. С. Ложкин Institute of Organic Chemistry, Ufa Science Center of the Russian Academy of Sciences, Ufa 450054
  • Д. В. Петров Institute of Organic Chemistry, Ufa Science Center of the Russian Academy of Sciences, Ufa 450054
  • В. А. Докичев Institute of Organic Chemistry, Ufa Science Center of the Russian Academy of Sciences, Ufa 450054
  • Ю. В. Томилов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991
  • О. М. Нефедов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991

DOI:

https://doi.org/10.1007/6607

Keywords:

1-(1-adamantyl)-2-diazoethanone, methyl acrylate, methyl 3-(1-adamantylcarbonyl)-4, 5-dihydroisoxazole-5-carboxylate, 5-dihydro-1H-pyrazole-5-carboxylate, methyl 3-(1-adamantylcarbonyl)-1H-pyrazole-5-carboxylate, 1, 3-dipolar cycloaddition

Abstract

The 1,3-dipolar addition of 1-(1-adamantyl)-2-diazoethanone to methyl acrylate gave methyl 3-(1-adamantylcarbonyl)-4,5-dihydro-1H-pyrazole-5-carboxylate from which there were prepared methyl 3-(1-adamantylcarbonyl) substituted 4,5-dihydroisoxazole-5- and 1H-pyrazole-5-carboxylates as well as the products of reduction of the latter at the keto- and ester groups.

How to Cite
Lozhkin, S. S.; Petrov, D. V.; Dokichev, V. A.; Tomilov, Yu. V.;  Nefedov, O. M. Chem. Heterocycl. Compd. 2009, 45, 937. [Khim. Geterotsikl. Soedin. 2009, 1180.]

For this article in the English edition see DOI 10.1007/s10593-009-0369-5

 

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Published

2022-02-16

Issue

No. 8 (2009)

Section

Original Papers