THE BEHAVIOR OF <i>p</i>-BIS{3-[N-(3-CHLOROBUTEN-2-YL)PYRROLIDINIO(PIPERIDINIO OR MORPHOLINIO)]PROPYN-1-YL}BENZENE DICHLORIDES IN AN AQUEOUS BASE MEDIUM

Authors

  • Э. О. Чухаджян Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Yerevan 0091
  • А. А. Хачатрян Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Yerevan 0091
  • А. Р. Геворкян Institute of Organic Chemistry, National Academy of Sciences of the Republic of Armenia, Yerevan 0091
  • Г. А. Паносян Molecular Structure Research Center, National Academy of Sciences of the Republic of Armenia, Yerevan 0014

DOI:

https://doi.org/10.1007/6749

Keywords:

benzo[5, 6-a, 5', 6'-c]bisspiro(4-methylisoindoline-2, 4'-morpholinium), p-bis(3-morpholinopropyn-1-yl)benzene, 6'-c]bis(2, 2-pentamethylene-4-methylisoindolinium) dichlorides, p-bis-{3-[N-(3-chlorobuten-2-yl)pyrrolidinio(piperidinio or morpholinio)]propyn-1-yl}benzene dichlorides, two-way dehydrochlorination-cyclization reaction

Abstract

In aqueous base medium p-bis{3-[N-(3-chlorobuten-2-yl)pyrrolidinio(piperidinio or morpholinio)]-propyn-1-yl}benzene dichlorides undergo a two-way dehydrochlorination-cyclization reaction to form benzo[5,6-a:5',6'-c]bis(2,2-tetramethylene- or -2,2-pentamethylene-4-methylisoindolinium) and benzo-[5,6-a:5',6'-c]bisspiro(4-methylisoindoline-2,4'-morpholinium) dichlorides.

How to Cite
Chukhajian, E. O.; Khachatryan, A. A.; Gevorkyan, A. R.; Panosyan, H. A.  Chem. Heterocycl. Compd. 2009, 45, 426. [Khim. Geterotsikl. Soedin. 2009, 546.]

For this article in the English edition see DOI 10.1007/s10593-009-0292-9

 

Published

2022-04-22

Issue

Section

Original Papers