DZHEMILEV REACTION IN THE SYNTHESIS OF FIVE-MEMBERED SULFUR AND SELENIUM HETEROCYCLES

Authors

  • В. А. Дьяконов Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • А. Г. Ибрагимов Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • Л. М. Халилов Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • А. А. Макаров Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • Р. К. Тимерханов Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • Р. А. Туктарова Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • О. А. Трапезникова Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075
  • Л. Ф. Галимова Russian Academy of Science Institution, Institute of Petroleum Chemistry and Catalysis of the Russian Academy of Sciences, Ufa 450075

DOI:

https://doi.org/10.1007/6776

Keywords:

aluminacyclopentanes, magnesacyclopentanes, selenophenes, tetrahydroselenophenes, tetrahydrothiophenes, thiophenes, metal complex synthesis

Abstract

A one-pot methods were developed for the synthesis of five-membered sulfur and selenium heterocycles based on the consecutive cyclometallation of olefins, allenes, and acetylenes using alkyl and haloalkyl derivatives of Al and Mg in the  presence of catalytic amounts of titanium and zirconium complexes to give the corresponding alumina- and magnesacarbocycles in situ, which, without further purification,
were introduced into reaction with sulfur or selenium, leading to various tetrahydrothiophenes, thiophenes, tetrahydroselenophenes, and selenophenes.

How to Cite
D'yakonov, V. A.; Ibragimov, A. G.; Khalilov, L. M.; Makarov, A. A.; Timerkhanov, R. K.; Tuktarova, R. A.; Trapeznikova, O. A.; Galimova, L. F.  Chem. Heterocycl. Compd. 2009, 45, 317. [Khim. Geterotsikl. Soedin. 2009, 393.]

For this article in the English edition see DOI 10.1007/s10593-009-0272-0

 

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Published

2022-04-27

Issue

No. 3 (2009)

Section

Original Papers