COORDINATION PROPERTIES OF 1,3-BENZOTHIAZOLES. FORMATION OF A POLYMERIC COMPLEX WITH SQUARE-PLANAR COORDINATION AROUND THE COPPER(II) ION IN THE REACTION OF CuCl<sub>2</sub>·6H<sub>2</sub>O WITH 1,2-BIS[2-(1,3-BENZOTHIAZOL-2-YL)PHENYLTHIO]ETHANE

Authors

  • Е. К. Белоглазкина M. V. Lomonosov Moscow State University, Moscow 119992
  • А. В. Шиморский M. V. Lomonosov Moscow State University, Moscow 119992
  • А. Г. Мажуга M. V. Lomonosov Moscow State University, Moscow 119992
  • Н. В. Зык M. V. Lomonosov Moscow State University, Moscow 119992

DOI:

https://doi.org/10.1007/7225

Keywords:

1, 3-benzothiazoles, coordination compounds, copper(II)

Abstract

It is shown that a coordination polymer is formed by  the reaction of 1,2-bis[2-(1,3-benzothiazol-2-yl)-phenylthio]ethane with copper(II) chloride in a mixture of ethanol and chloroform at room temperature. The structure of the polymer has been determined  by  X-ray  crystallography. The copper atom in the coordination polymer has a square-planar ligand environment and is coordinated to the nitrogen atoms of the benzothiazole rings of two different molecules of ligand and two chloride anions.

How to Cite
Beloglazkina, E. K.; Shimorskiy, A. V.; Majouga, A. G.; Zyk, N. V.  Chem. Heterocycl. Compd. 2008, 44, 1284. [Khim. Geterotsikl. Soedin. 2008, 1576.]

For this article in the English edition see DOI 10.1007/s10593-009-0182-1


Downloads

Published

2022-11-29

Issue

No. 10 (2008)

Section

Original Papers