STRUCTURAL INVESTIGATION OF 1-(N,N-DIMETHYLAMINOMETHYL)SPIROBI(3-OXO-2,5-DIOXA-1-SILACYCLOPENTAN)ATES

Authors

  • С. Беляков Latvian Institute of Organic Chemistry, LV-1006 Riga
  • Н. Ерчак A. S. Pushkin Brest State University, 224665 Brest University of Podlasie, 08-110 Siedlce
  • С. Жеймоте Latvian Institute of Organic Chemistry, LV-1006 Riga
  • М. Флейшер Latvian Institute of Organic Chemistry, LV-1006 Riga
  • Э. Лукевиц Latvian Institute of Organic Chemistry, LV-1006 Riga

DOI:

https://doi.org/10.1007/7305

Keywords:

electrostatically stabilized silanates, PM6 method, X-ray structural analysis

Abstract

1-[(N,N-Dimethyl)aminomethyl]spirobi(3-oxo-2,5-dioxa-1-silacyclopentan)ate and  1-(N,N-dimethyl)-aminomethyl]spirobi(4,4-dimethyl-3-oxo-2,5-dioxa-1-silacyclopentan)ate are representatives of amino-methylspirobi(3-oxo-2,5-dioxa-1-silacyclopentan)ates,  which are electrostatically stabilized silanates (ES silanates). X-ray diffraction structural analysis and quantum-chemical calculations were used in a structural study of these compounds. The factors  affecting the geometry of these molecules  are discussed.

How to Cite
Belyakov, S.; Erchak, N.; Zheimote, S.; Fleisher, M.; Lukevics, E.  Chem. Heterocycl. Compd. 2008, 44, 1520. [Khim. Geterotsikl. Soedin. 2008, 1873.]

For this article in the English edition see DOI 10.1007/s10593-009-0218-6


Downloads

Published

2023-01-05

Issue

No. 12 (2008)

Section

Original Papers