REACTION OF 1,5-DIARYL-3-HYDROXY-4-METHYLSULFONYL-3-PYRROLIN-2-ONES WITH UREA, HYDRAZINE, ETHYLENEDIAMINE, AND <i>o</i>-PHENYLENEDIAMINE

Authors

  • В. Л. Гейн Perm State Pharmaceutical Academy, Perm 614990
  • А. В. Катаева Perm State Pharmaceutical Academy, Perm 614990
  • Л. Ф. Гейн Perm State Pharmaceutical Academy, Perm 614990

DOI:

https://doi.org/10.1007/7333

Keywords:

3-amino-1, 5-diaryl-4-methylsulfonyl-3-pyrrolin-2-ones, 2, 3-diaryl-4-methylsulfonylpyrrolo[2, 3-b]quinoxalines, binucleophilic reagents

Abstract

With urea 1,5-diaryl-3-hydroxy-4-methylsulfonyl-3-pyrrolin-2-ones form the 3-amino derivatives of pyrrolones. In reactions with hydrazine hydrate and ethylenediamine the corresponding salts are formed. With ethylenediamine at 180-185°C the double salt of 3-hydroxy-4-methylsulfonyl-1,5-diphenyl-3-pyrrolin-2-one forms N,N′-di(4-methylsulfonyl-1,5-diphenyl-3-pyrrolin-2-on-3-yl)-ethylenediamine. The reaction with o-phenylenediamine gives 2,3-diaryl-4-methylsulfonylpyrrolo-[2,3-b]quinoxalines.

How to Cite
Gein, V. L.; Kataeva, A. V.; Gein, L. F.  Chem. Heterocycl. Compd. 2007, 43, 1385. [Khim. Geterotsikl. Soedin. 2007, 1631.]

For this article in the English edition see DOI 10.1007/s10593-007-0214-7


Published

2023-01-18

Issue

Section

Original Papers