SYNTHESIS AND STRUCTURE OF TRIS(5-PHENYLTETRAZOL-1-YL)METHANE

Authors

  • Р. Е. Трифонов Saint Petersburg State Technological Institute (Technical University), Saint Petersburg 190013
  • Г. В. Гурская V. A. Engelgardt Institute of Molecular Biology, Russian Academy of Sciences, Moscow 119991
  • А. В. Гаенко Department of Theoretical Chemistry, Chemical Center, Lund University, Lund, S-221 00
  • В. Е. Заводник L. Ya. Karpov Research Institute for Physical Chemistry, Moscow 105064
  • В. А. Островский Saint Petersburg State Technological Institute (Technical University), Saint Petersburg 190013

DOI:

https://doi.org/10.1007/7643

Keywords:

polynuclear heterocycles, tetrazole, X-ray structural analysis, theoretical calculations by the DFT method

Abstract

The interaction of 5-phenyltetrazolate anion with chloroform in strongly alkaline medium leads  to  the formation of tris(5-phenyltetrazol-1-yl)methane and 2-dichloromethyl-5-phenyltetrazole. The  structures of tris(5-phenyltetrazol-1-yl)-methane and of its isomer tris(5-phenyltetrazol-2-yl)methane have been investigated by X-ray structural analysis  and  theoretical calculations carried out on the B3LYP/6-31G** basis.

How to Cite
Trifonov, R. E.; Gurskaya, G. V.; Gaenko, A. V.; Zavodnik, V. E.;  Ostrovskii, V. A.  Chem. Heterocycl. Compd. 2007, 43, 320. [Khim. Geterotsikl. Soedin. 2007, 398.]

For this article in the English edition see DOI 10.1007/s10593-007-0048-3


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Published

2023-03-30

Issue

No. 3 (2007)

Section

Original Papers