2-ISOXAZOLINES WITH AN ELECTRON-ACCEPTOR SUBSTITUENT AT C(5) IN REACTIONS WITH NUCLEOPHILIC REAGENTS

Authors

  • Е. В. Королева Institute of the Chemistry of New Materials, Belarus National Academy of Sciences, Minsk 220141
  • Н. Ф. Бондарь Belorussian Agricultural Technological University, Minsk 220050
  • Я. М. Каток Belorussian State Technological University, Minsk 220050
  • Н. А. Чеканов Institute of the Chemistry of New Materials, Belarus National Academy of Sciences, Minsk 220141
  • Т. В. Чернихова Institute of the Chemistry of New Materials, Belarus National Academy of Sciences, Minsk 220141

DOI:

https://doi.org/10.1007/7649

Keywords:

derivatives of 2-isoxazoline, dimsyl sodium, molybdenum hexacarbonyl, K-selectride, cyclodecomposition

Abstract

Depending on the substituent at position 5 of the  heterocycle, reaction of 2-isoxazolines with K-selectride, molybdenum hexacarbonyl, dimsyl sodium, and butyl lithium gave 1,3-cyclo-decomposition, aromatization of the isoxazoline ring, or reduction of the functional groups in the substituted isoxazolines.

 

How to Cite
Koroleva, E. V.; Bondar, N. F.; Katok, Ya. M.; Chekanov, N. A.; Chernikhova, T. V.  Chem. Heterocycl. Compd. 2007, 43, 362. [Khim. Geterotsikl. Soedin. 2007, 447.]

For this article in the English edition see DOI 10.1007/s10593-007-0053-6

 

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Published

2023-03-31

Issue

No. 3 (2007)

Section

Original Papers