SILAZANES PLUS MCl4 -SUBSTITUTION <i>vs</i>. REARRANGEMENT REACTIONS

Authors

  • C. Lehnert TU Bergakademie Freiberg, Institut für Anorganische Chemie, 09599 Freiberg
  • J. Wagler TU Bergakademie Freiberg, Institut für Anorganische Chemie, 09599 Freiberg
  • E. Kroke TU Bergakademie Freiberg, Institut für Anorganische Chemie, 09599 Freiberg
  • G. Roewer TU Bergakademie Freiberg, Institut für Anorganische Chemie, 09599 Freiberg

DOI:

https://doi.org/10.1007/7731

Keywords:

1, 3-diphenyl-1, 3, 3-tetramethyldisilazane, 5, 5-hexamethylcyclotrisilazane, rearrangement, substitution

Abstract

Novel silicon and tin compounds were synthesized by the reaction of lithium salts of 1,3-di-phenyl-1,1,3,3-tetramethyldisilazane H(DPTMDS)  and 1,1,3,3,5,5-hexamethylcyclotrisilazane H3(HMCTS) with SiCl4 and SnCl4, respectively. The reactions with H(DPTMDS) yield the substitution products (DPTMDS)2SiCl2 and (DPTMDS)2SnCl2. In contrast, the reactions with the cyclic silazane H3(HMCTS) lead to a large variety of  products due to a competition of substi-tution reactions and ring contractions. The resulting new compounds were characterized by ele-mental analyses, NMR spectroscopy, and single crystal X-ray structure analyses.

How to Cite
Lehnert, C.; Wagler, J.; Kroke, E.; Roewer, G.  Chem. Heterocycl. Compd. 2006, 42, 1574. [Khim. Geterotsikl. Soedin. 2006, 1845.]

For this article in the English edition see DOI 10.1007/s10593-006-0281-1

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Published

2023-04-25

Issue

No. 12 (2006)

Section

Original Papers