CHEMISTRY OF 2-HETARYLBENZIMIDAZOLES. 10. SYNTHESIS AND PROPERTIES OF 2-(3'-FURYL)-1-METHYL-1H-BENZIMIDAZOLE

Authors

  • А. А. Ачкасова South Russian State Technical Institute, 346428 Novocherkassk
  • М. М. Ельчанинов South Russian State Technical Institute, 346428 Novocherkassk
  • А. А. Милов Physical and Organic Chemistry Research Institute, 344104 Rostov-on-Don
  • Б. С. Лукьянов Physical and Organic Chemistry Research Institute, 344104 Rostov-on-Don

DOI:

https://doi.org/10.1007/8112

Keywords:

2-(3'-furyl)-1-methyl-1H-benzimidazole, quantum-chemical calculations, substituent orientation, electrophilic substitution reactions

Abstract

A study was carried out on the electrophilic substitution reactions such as chloromethylation, bromination, sulfonation, nitration, and acylation  of 2-(3'-furyl)-1-methyl-1H-benzimidazole in acid media. All these reactions proceed at C(2) and C(5) of the furan ring. Quantum-chemical calculations of the three-dimensional structure of such heterocyclic systems are given.

How to Cite
Achkasova, A. A.; Elchaninov, M. M.; Milov, A. A.; Lukyanov, B. S.  Chem. Heterocycl. Compd. 2005, 41, 1494. [Khim. Geterotsikl. Soedin. 2005, 1815.]

For this article in the English edition, see DOI 10.1007/s10593-006-0026-1


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Published

2023-10-11

Issue

No. 12 (2005)

Section

Original Papers