PSEUDOROTATION AND BARRIERS TO INVERSION OF 1,3,2-DIOXABORINANE RINGS

Authors

  • В. В. Кузнецов A. V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa 65080
  • А. Н. Новиков A. V. Bogatsky Physico-Chemical Institute, National Academy of Sciences of Ukraine, Odessa 65080

Keywords:

1,3,2-dioxaborinanes, conformer, interconversion barrier, transition state

Abstract

It has been shown by empirical, semiempirical, and nonempirical methods that the interconversion of the rings of 1,3,2-dioxaborinanes goes via transition state with the 2,5-twist form and differs from the monotypic substituted 1,3-dioxanes in having a lower potential barrier.

How to Cite
Kuznetsov, V. V.; Novikov, A. N. Chem. Heterocycl. Compd. 2003, 39, 263. [Khim. Geterotsikl. Soedin. 2003, 295.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1023788912799

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Published

2003-02-25

Issue

No. 2 (2003)

Section

Original Papers