CATALYTIC HYDROSILYLATION OF FURAN, THIOPHENE, AND PYRIDINE ALDIMINES

Abstract

The addition of hydrosilanes (HSiEt₃, HSiMe₂Ph, H₂SiPh₂) to the CH=N bond of heterocyclic azomethines has been studied in the presence of monovalent complexes of rhodium and palladium. The effect on the reaction of the CF₃ group of the aldimines, which were obtained from O-, S-, and N-heteroaromatic aldehydes and 2-trifluoromethylaniline, has been clarified, as were other regularities of the processes being studied. A series of corresponding furans, thiophenes, and pyridine amines has been synthesized.

How to Cite
Iovel, I.; Golomba, L.; Popelis, J.; Grinberga, S.; Lukevics, E. Chem. Heterocycl. Compd. 2003, 39, 49. [Khim. Geterotsikl. Soedin. 2003, 52.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1023012523372