INTERACTION OF (<i>Z</i>)-1-HYDROXY-3-METHYLPENT-2-EN-4-YNE WITH CH<sub>2</i>O–SECONDARY AMINE SYSTEM. NEW ROUTE TO FORM α-(1,3-BIS-N,N-DIALKYLAMINOPROP-2-YL)FURANS

Authors

  • M. B. Мавров N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913
  • Н. И. Симирская N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 117913

Keywords:

aminoalkylation, bis(dialkylamino)furans, (Z)-vinylacetylenic alcohol, heterocyclization

Abstract

The aminomethylation of (Z)-1-hydroxy-3-methylpent-2-en-4-yne with paraformaldehyde and secondary amines has been studied. The reaction was established to begin with the formation of vinylacetylenic monoadducts, which under the action of the aminomethylating agent are heterocyclized into the corresponding α-(1,3-bis-N,N-dialkylaminoprop-2-yl)-β-methylfurans.

How to Cite
Mavrov, M. V.; Simirskaya, N. I. Chem. Heterocycl. Compd. 2001, 37, 276. [Khim. Geterotsikl. Soedin. 2001, 305.]

For this article in the English edition, see DOI https://doi.org/10.1023/A:1017594613654

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Published

2001-03-25

Issue

No. 3 (2001)

Section

Original Papers