

2-Halo-2-organyl-4H-benzo[d][1,3,2]dioxasilin-4-ones

Abstract
Original method has been developed for the preparation of previously unknown cyclic organosilicon esters of salicylic acid, containing halogen–silicon bonds. This method is based on the reaction of trimethylsilyl ester of 2-(trimethylsiloxy)benzoic acid with organylhalosilanes RR1SiXY under mild conditions, where R, R1 = Cl, Me, CH=CH2, Ph; X, Y = Cl, F.
How to Cite
Basenko, S. V.; Zelenkov, L. E. Chem. Heterocycl. Compd. 2015, 51, 295. [Khim. Geterotsikl. Soedin. 2015, 51, 295.]
For this article in the English edition see DOI 10.1007/s10593-015-1698-1
Keywords
4H-benzo[d][1,3,2]dioxasilin-4-ones; cyclic esters; organosilicon esters; organylfluorosilanes; organylchlorosilanes; salicylic acid
Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv