2-Halo-2-organyl-4<i>H</i>-benzo[<i>d</i>][1,3,2]dioxasilin-4-ones

Authors

  • Сергей В. Басенко 1A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Лев Е. Зеленков 1A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/2160

Keywords:

4H-benzo[d][1, 3, 2]dioxasilin-4-ones, cyclic esters, organosilicon esters, organylfluorosilanes, organylchlorosilanes, salicylic acid

Abstract

Original method has been developed for the preparation of previously unknown cyclic organosilicon esters of salicylic acid, containing halogen–silicon bonds. This method is based on the reaction of trimethylsilyl ester of 2-(trimethylsiloxy)benzoic acid with organylhalosilanes RR1SiXY under mild conditions, where R, R1 = Cl, Me, CH=CH2, Ph; X, Y = Cl, F.

How to Cite
Basenko, S. V.; Zelenkov, L. E. Chem. Heterocycl. Compd. 2015, 51, 295. [Khim. Geterotsikl. Soedin. 2015, 51, 295.]

For this article in the English edition see DOI 10.1007/s10593-015-1698-1

 

Author Biographies

Сергей В. Басенко, 1A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Сергей Владимирович Басенко

д.х.н., в.н.с., лаборатории элементоорганических соединений

Лев Е. Зеленков, 1A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

Лев Евгеньевич Зеленков

к.х.н., н.с. лаборатории непредельных гетероатомных соединений

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Published

2015-02-05

Issue

Vol. 51 No. 3 (2015)

Section

Original Papers