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2-AROYLHEXANONES IN THE SYNTHESIS OF AZOLES

А. Г. Михайловский, З. Г. Алиев, Н. Г. Базина, А. А. Пантюхин, М. И. Вахрин

Abstract


2-Aroylcyclohexanones, obtained from piperidinocyclohexene, react with hydrazine, hydroxylamine, and o-phenylenediamine to give the corresponding derivatives of bicyclic heterocycles – indazole, 2,1‑benzisoxazole, and 2-spiro-cyclohexylbenzimidazole. The structure of a derivative of benzyloxazole has been determined by X-ray crystallography.

How to Cite
Mikhailovskii, A. G.; Aliev, Z. G.; Bazina, N. G.; Pantyukhin, A. A.; Vakhrin, M. I. Chem. Heterocycl. Compd. 2010, 46, 730. [Khim. Geterotsikl. Soedin. 2010, 905.]

For this article in the English edition see DOI 10.1007/s10593-010-0576-0


Keywords


3-aryl-4,5,6,7-tetrahydro-2,1-benzisoxazoles; 3-aryl-4,5,6,7-tetrahydroindazoles; 2-aroylcyclohexanones; hydrazine; hydroxylamine; piperidinocyclohexene; 2-spiro-(2-aroylcyclohexyl)benzimidazolidines; o-phenylenediamine; X-ray crystallography

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