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N-ALKYLATION OF NITROGEN HETEROCYCLES WITH α-DIAZOCARBONYL COMPOUNDS

Игорь В. Соловьев, Даниил Д. Жуковский, Дмитрий В. Дарьин, Михаил Ю. Красавин
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Abstract


Examples of the use of α-diazocarbonyl compounds in the N–H insertion reactions with the formation of the products of selective N-alkylation of various five-membered nitrogen heterocycles and their derivatives are considered. The literature data is systematized according to the number of N atoms in the heterocycle. The review contains information published in the period from 2003 to 2020.

Authors: Igor V. Solovyev, Daniil D. Zhukovsky, Dmitry V. Dar'in, Mikhail Yu. Krasavin*

N-alkylation of various five-membered nitrogen heterocycles and their derivatives are considered. The literature data is systematized
according to the number of N atoms in the heterocycle. The review contains information published in the period from 2003 to 2020.

Keywords


азотистые гетероциклы; α-диазокарбонильные соединения; алкилирование; внедрение по связи N–H

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