<i>N</i>-ALKYLATION OF NITROGEN HETEROCYCLES WITH α-DIAZOCARBONYL COMPOUNDS

Authors

  • Игорь В. Соловьев Institute of Chemistry, Saint Petersburg State University, 26 Universitetsky Ave., Petergof, Saint Petersburg 198504
  • Даниил Д. Жуковский Institute of Chemistry, Saint Petersburg State University, 26 Universitetsky Ave., Petergof, Saint Petersburg 198504
  • Дмитрий В. Дарьин Institute of Chemistry, Saint Petersburg State University, 26 Universitetsky Ave., Petergof, Saint Petersburg 198504
  • Михаил Ю. Красавин Institute of Chemistry, Saint Petersburg State University, 26 Universitetsky Ave., Petergof, Saint Petersburg 198504

DOI:

https://doi.org/10.1007/5748

Keywords:

азотистые гетероциклы, α-диазокарбонильные соединения, алкилирование, внедрение по связи N–H

Abstract

Examples of the use of α-diazocarbonyl compounds in the N–H insertion reactions with the formation of the products of selective N-alkylation of various five-membered nitrogen heterocycles and their derivatives are considered. The literature data is systematized according to the number of N atoms in the heterocycle. The review contains information published in the period from 2003 to 2020.

Authors: Igor V. Solovyev, Daniil D. Zhukovsky, Dmitry V. Dar'in, Mikhail Yu. Krasavin*

N-alkylation of various five-membered nitrogen heterocycles and their derivatives are considered. The literature data is systematized
according to the number of N atoms in the heterocycle. The review contains information published in the period from 2003 to 2020.

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Published

2020-08-18

Issue

Vol. 56 No. 7 (2020): Synthesis and transformations of heterocycles under electrophilic conditions

Section

Review Articles