

SYNTHESIS OF NOVEL 1,4-OXATHIINE DERIVATIVES CONTAINING POLYFLUOROALKYL SUBSTITUENTS AT POSITIONS 2 AND 6

Abstract
Dehydrofluorination of bis(1,1-dihydropolyfluoroalkyl) sulfides with lithium hydroxide in morpholine occurs in a controlled manner with the formation of a new type of bis(enamine) sulfides, bis[2-(morpholin-4-yl)polyfluoroalk-1-en-1-yl]sulfanes, hydrolysis and subsequent fluorination of which leads to the production of novel fluorine-containing 1,4-oxathiine derivatives with divalent sulfur.
Keywords
1,4-dihydrooxathiines; enamines; 1,4-oxathianes; 1,4-oxathiines; sulfides; dehydrofluorination.
Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv