Dehydrofluorination of bis(1,1-dihydropolyfluoroalkyl) sulfides with lithium hydroxide in morpholine occurs in a controlled manner with the formation of a new type of bis(enamine) sulfides, bis[2-(morpholin-4-yl)polyfluoroalk-1-en-1-yl]sulfanes, hydrolysis and subsequent fluorination of which leads to the production of novel fluorine-containing 1,4-oxathiine derivatives with divalent sulfur.
Author Biographies
Ярослав С. Бородкин, Institute of Organic Chemistry, National Academy of Sciences of Ukraine,
5 Murmanska St., Kyiv 02660, Ukraine
Отдел химии органических соединений серы, аспирант
Юрий Г. Шермолович, Institute of Organic Chemistry, National Academy of Sciences of Ukraine,
5 Murmanska St., Kyiv 02660, Ukraine
д.х.н, профессор, заведущий отдела химии органических соединений серы
