Formation of the pyrroline-N-oxide ring by the reaction of isonitrosoketones with enamines and some conversions of the pyrroline-N-oxides obtained

Authors

  • B. А. Самсонов Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • Л. Б. Володарский Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • И. Ю. Бaгрянская Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090
  • Ю. B. Гатилов Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk 630090

Abstract

Compounds containing the pyrroline-N-oxide ring are obtained when isonitrosoketones — 2,6-dihydroxyiminocyclohexanone and ω-isonitrosoacetophenone — react with enamines. The compounds obtained behave as synthetic equivalents of 1,4-dicarbonyl compounds when undergoing reaction with amines, hydrazine, and hydroxylatnine.

How to Cite
Samsonov, V. A.; Volodarskii, L. B.; Bagryanskaya, I. Y.; Gatilov, Yu. V. Chem. Heterocycl. Compd. 1996, 32, 907. [Khim. Geterotsikl. Soedin. 1996, 1055.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01176965

Published

1996-08-25

Issue

Section

Original Papers