Synthesis of mono- and disubstituted tetra(<i>tert</i>-butyl)porphyrazines

Authors

  • Е. А. Макарова Scientific-Research Institute for Organic Itermediates and Dyes, Moscow 103787
  • В. Н. Копраненков Scientific-Research Institute for Organic Itermediates and Dyes, Moscow 103787
  • В. К. Шевцов Scientific-Research Institute for Organic Itermediates and Dyes, Moscow 103787
  • E. А. Лукьянец Scientific-Research Institute for Organic Itermediates and Dyes, Moscow 103787

Abstract

Bromination of tetra(tert-butyl)porphyrazine by N-bromosuccinimide in chloroform results in the formation of mono- and dibromides, substitution for the bromine atoms of which produced the corresponding cyano, phenoxy, phenylthio, styryl, phenylethynyl and piperidino derivatives. From the monobromide and 2,2-bis(p-hydroxyphenyl)propane, the dimeric porphyrazine 2,2-bis[p-tetra(tert-butyl)porphyrazyloxyphenyl]propane was similarly obtained.

How to Cite
Makarova, E. A.; Kopranenkov, V. N.; Shevtsov, V. K.; Luk'yanets, E. A. Chem. Heterocycl. Compd. 1994, 30, 1043. [Khim. Geterotsikl. Soedin. 1994, 1206.]

For this article in the English edition, see DOI https://doi.org/10.1007/BF01171160

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Published

1994-09-25

Issue

No. 9 (1994)

Section

Original Papers